Why not? Its your money right? if you ask for the cash the bank cant refuse with it. Given enough notice they will give it to you in cash.
I was about to call bullshit on whether all that is legal tender but it could very well be. The bands are for all $10,000.....i doubt that pictured there is the full $100m coz that would mean 10,000 of those wads of cash. doesnt look like that many